Thinaharan, C.; Aswal, D. K.; Singh, A.; Bhattacharya, S.; Joshi, N.; Gupta, S. K.; Yakhmi, J. V. (TPPED)
Source
Crystal Research and Technology, 2004. Vol. 39 (7): pp. 572-576
ABSTRACT
We have grown single crystals of recently discovered thermoelectric oxide material NaxCoO2 using NaCl flux. Crystals of sizes upto 1.5 x 1.5 x 1.5 mm3 having different morphological habits were reproducibly grown. The atomic force microscopic studies show that along c-axis crystals grow via 2D layer-by-layer mechanism. The X-ray diffraction analyses show that grown crystals are rich in Na content as compared to the starting charge indicating that NaCl flux also acts as a source of Na. The resistivity of the crystals exhibited a linear temperature dependence in the region between 30 and 300 K.