BARC/PUB/2002/0334

 
 

Fourier-transform spectroscopic study of the rotational intensity distribution in the firrst positive B3∏g–A3+u band system of the nitrogen molecule

 
     
 
Author(s)

Mishra, A. P.; Narayanan, O.; Kshirsagar, R. J.; Bellary, V. P.; Balasubramanian, T. K.
(Spect. Div.)

Source

Journal of Quantitative Spectroscopy & Radiative Transfer, 2002. Vol. 72: pp. 665-676

ABSTRACT

In the present work we have studied the rotational intensity distribution in the 0 – 0, 0 –1 and 1–3 bands of the B3∏g–A3+u system of N2 recorded on a Fourier transform spectrometer .The effective Hamiltonian used by Roux et al. (J .Mol. Spectrosc. 97 (1983) 253) for reduction of the experimental line position data to molecular parameters, is found to be adequate in reproducing the observed line intensities .To enhance the accuracy of the theoretical line intensity calculations, it proved necessary to use rotation-dependent Frank–Condon factor .Using the calculated intensities, it was possible to identify certain rotational lines belonging to the weakest branches Q13 and Q31, not reported before.

 
 
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