BARC/PUB/2016/1308

 
 

Boosting thermoelectric performance of p-type SiGe alloys through in-situ metallic YSi2 nano inclusions

 
     
 
Author(s)

Ahmad, S.; Singh, A.; Bohra, A.; Basu, R.; Bhattacharya, S.; Bhatt, R.; Meshram, K. N.; Debnath, A. K.; Aswal, D. K.; Gupta, S. K.; and others
(TPD;ApSD;ChD)

Source

Nano Energy, 2016. Vol. 27: pp. 282-297

ABSTRACT

Incorporation of metallic yttrium silicide nanoparticles in p-type SiGe alloys matrix is demonstrated to enhance their thermoelectric performance.In this work,we report a thermoelectric figure-of-merit (ZT) of ~1.81 (at 1100 K)in p-type SiGe alloys(that is ~34% higher as compared to earlier best reported ZT value)by intentional incorporation of metallic yttrium silicide (YSi2) nano-inclusions.The YSi2 nano-inclusions were in-situ formed in p-type SiGe matrix by its reaction with Y2O3 nanoparticles (≤6 wt%) during vacuum hot pressing at 1423K under a pressure of 50kg/cm2. YSi2 nanoinclusions formcoherent interfaces with SiGe matrix and facilitate are ductionin the grain size of SiGe.These factors cause a strong suppression of thermal conductivity (κSiGe~3.86 Wm-1 K-1 and κSiGe-YSi2 ~2.38Wm-1 K-1 at 1100 K) without affecting the power factor, and therefore, results in a dramatic enhancement of ZT. In addition, SiGe-YSi2 nanocomposites exhibit enhancement in mechanical hardness,enhanced average ZT as well as compatibility factor, which are additional useful characteristics for practical applications.

 
 
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