BARC/PUB/2016/0165

 
 

Radiation stability of Gd2Zr2O7: Effect of stoichiometry and structure

 
     
 
Author(s)

Kumari, R.; Kulriya, P. K.; Grover, V.; Shukla, R.; Saravanan, K.; Mohapatra, S.; Tyagi, A. K.; Avasthi, D. K.
(ChD)

Source

Ceramics International, 2016. Vol. 42: pp. 103-109

ABSTRACT

The dependence of radiation stability of Gd2Zr2O7 on stoichiometry and structure under swift heavy ion irradiation was investigated. Gd2Zr2O7, lies on the borderline of pyrochlore to fluorite phase transition, hence, it is highly sensitive to variations in the composition and/or synthesis conditions. The Gd2Zr2O7 was synthesized in two sets (Set-A and-B) by solid state synthesis and gel combustion yielding different phases and stoichiometry as confirmed by Resonant Rutherford back scattering spectrometry (RRBS) and field emission scanning electron microscopy (FESEM). Both sets of Gd2Zr2O7 were irradiated with 120MeV Au ions with fluences varying from 3X1011 to 1X1014 ions/cm2. The pristine and irradiated samples were studied by X-ray diffraction ne upto the highest fluence 1014 ions/cm2 employed, where as Set-B sample having anion-deficient fluorite structure lost crystallinity at the fluence of 5X1013 ions/cm2, as revealed by in-situ XRD experiment. The in-situ XRD along with Raman studies elucidated that sample synthesized using solid state reaction process exhibits better stability under swift heavy ion irradiation, implying that the sample with perfect stoichio metric pyrochlore structure possess better radiation stability.

 
 
SIRD Digital E-Sangrahay