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Author(s) |
Kumar, S. A.; Thakur, N.; Parab, H. J.; Pandey, S. P.; Shinde, R. N.; Pandey, A. K.; Kumar, S. D.; Reddy, A. V. R. (ACD;RCD)
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Source |
Analytica Chimica Acta, 2014. Vol. 851: pp. 87-94 |
ABSTRACT
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A
visual strip has been developed for sensing iron in different aqueous
samples like natural water and fruit juices. The sensor has been
synthesized by UV-radiation induced graft polymerization of acrylamide
monomer in microporous poly(propylene) base. For physical immobilization
of iron selective reagent, the in situ polymerization of acrylamide has
been carried out in the presence of 1,10-phenanthroline. The loaded
strip on interaction with Fe(II) in aqueous solution turned into orange
red color and the intensity of the color was found to be directly
proportional to the amount of Fe(II) in the aqueous sample. The minimal
sensor response with naked eye was found for 50 ng mL-1 of Fe in 15 min of interaction. However, as low as 20 ng mL-1 Fe could be quantified using a spectrophotometer. The detection limit calculated using the 3s/S criteria, where ‘s’ is the standard deviation of the absorbance of blank reagent loaded strip and ‘S’ is the slope of the linear calibration plot, was 1.0 ng mL-1 . The strip was applied to measure Fe in a variety of samples such as ground water and fruit juices. |
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