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Author(s) |
Dias, E. T.; Priolkar, K. R.; Nigam, A. K.; Singh, Ripandeep; Das, Amitabh; Aquilanti, G. (SSPD)
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Source |
Physical Review-B, 2017. Vol. 95 (14): pp. 144418.1-144418.8 |
ABSTRACT
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The existence of nonergodic ground states is considered as a precursor to a first-order long-range magnetostructural transformation. Mn3Ga0.45Sn0.55Clies compositionally between two compounds, Mn3GaC and Mn3SnC, undergoing first-order magnetic transformation. However, Mn3Ga0.45Sn0.55C, which crystallizes in a single-phase cubic structure, exhibits more than one long-range magnetic transition. Using a combination of magnetization, ac susceptibility, neutron diffraction, and x-ray-absorption fine-structure techniques, it is shown that, although Mn3Ga0.45Sn0.55C exhibits long-range magnetic order, it presents a cluster glassy ground state due to formation of magnetically ordered Ga-rich and Sn-rich clusters. The clusters are big enough to present signatures of long-range magnetic order but are distributed in a way that limits interactions between two clusters of the same type, leading to a frozen magnetic state at low temperatures. The main reason for such a cluster-glass state is the difference in the local structure of Mn atoms that find themselves in Ga-rich and Sn-rich clusters. |
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