BARC/PUB/2003/0488

 
 

Absorption intensities of the multipole-field-induced zero-phonon transitions in solid HD, HT, and DT

 
     
 
Author(s)

Mishra, A. P.; Field, R. W.; Bhaskara Rao, S. V. N.; DSouza, R.; Balasubramanian, T. K.
(Spect. Div.)

Source

Physical Review-B, 2003. Vol. 67 (13): Article no. 134305

ABSTRACT

Closed-form theoretical expressions are derived for the integrated absorption coefficient of various zerophonon single and double transitions in heteronuclear isotopic variants of hydrogen in condensed phase. Theoretical analysis predicts a different kind of double transition in the spectra of solid HD, HT, and DT, where the rotational energy of one molecule changes by three quanta and the rotational energy of another molecule simultaneously changes by at least three quanta. The expressions for double transitions given in this paper may, for example, be applied to double transitions involving para-H2–HD or ortho-D2–HD pairs.

 
 
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