BARC/PUB/2003/0211

 
 

Thermodynamic stability of RuTe2 solid by vapor pressure study

 
     
 
Author(s)

Basu, M. A.; Shirsat, A. N.; Mishra, R.; Kerkar, A. S.; S. C. Kumar; Bharadwaj, S. R.; Das, D.
(ApCD;ACD)

Source

Journal of Alloys and Compounds, 2003. Vol. 352 (42767): pp. 140-142

ABSTRACT

The vaporization behavior of the intermetallic compound RuTe2(s) was studied in the temperature range of 831–1148 K by the Knudsen effusion technique. As a prerequisite to the study, the nature of the vaporization equilibrium was first obtained. Phase analysis of the partially evaporated sample of RuTe2(s) from thermogravimetric experiment carried out in inert environment showed the TG residue to be a biphasic mixture of Ru(s) and RuTe2(s). This result together with the available thermodynamic information of Te vapor revealed that the compound incongruently volatilize as RuTe2 (s)=Ru(s)+Te2(g). The equilibrium vapor pressure of Te2(g) derived from the measurement at the different temperatures could be expressed as ln(p/Pa)(±0.33) = – 33231.2/T + 33.67 (831 ≤ T/K ≤ 1148). The result of this study is discussed in the light of the reported data on the intermetallic compound.

 
 
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