We report structural and electrochemical properties of nanostructured cobalt free La₂CuMnO₆ synthesized via facile hydrothermal process. The X-ray diffraction shows formation of pervoskite orthorhombic crystal phase with Pbnm symmetry and lattice parameters as a=5.526 Å, b=5.482 Å and c=7.653 Å, respectively. The Xray photoelectron spectroscopy exhibits the presence of La³⁺, Cu²⁺, and Mn³⁺/Mn⁴⁺ ions on the surface of La₂CuMnO₆. The electrochemical performance of nanostructured cobalt free La₂CuMnO₆ investigated by cyclic voltammetry and chronopotentiometry techniques exhibit pseudo capacitive nature of the cobalt free La₂CuMnO₆. The calculated value of specific capacitance is 205.5 F/g at current density of 0.25 A/g; with ~78% specific capacitance retention, after 1000 cycles at 1.50 A/g.