The temperature dependent current–voltage (J–V) characteristics of 20 nm thick iron-phthalocyanine films are investigated in the temperature range of 300–30 K, and in the bias range of ±200 V. In the temperature range of 300–100 K, the charge transport is governed by bulk-limited processes with a bias dependent crossover from Ohmic (J ~ V) to exponentially distributed shallow trap mediated space–charge-limited conduction (J ~ V^α, α≥2) to space–charge-limited conduction with field enhanced mobility (ln μ ~ E^1/2). However, at temperatures less than 100 K, the charge transport is electrode-limited, and undergoes a bias dependent transition from Schottky (ln J ~ V^1/2) to multistep tunneling. From shallow trap mediated space–charge-limited conduction data the estimated room temperature mobility was found to be ~1.9 cm² V^-1 s^-1. The high mobility of films is attributed to better structural organization due to the face-on stacking of molecules, which is supported by x-ray diffraction and UV–visible spectroscopy data.