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Author(s) |
Sharma, S.; Panja, S.; Ghosh, S. K.; Dhami, P. S.; Gandhi, P. M. (BOD;FRD)
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Source |
Journal of Hazardous Materials, 2016. Vol. 305: pp. 171-177 |
ABSTRACT
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A conformationally constrained diamide, (N,N,N´,N´-tetra-2-ethylhexyl) 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxamide (OBDA) was found to transport Am(III) from HNO3 medium across a Supported Liquid Membrane with good transport rate, diffusion coefficient and selectivity over fission products. Am(III) is one of the most hazardous radionuclide present in nuclear fuel cycle. A new conformation-ally constrained diamide, (N,N,N´,N´-tetra-2-ethylhexyl)7-oxabicyclo[2.2.1]heptane-2,3-dicarboxamide(OBDA) was studied for Am(III) transport from HNO3 medium across a Supported Liquid Membrane. Transport rate was observed to be significantly fast with ∼95% transport of Am(III) within 1 h using 0.1 MOBDA in the presence of 15% isodecyl alcohol (IDA)/n-dodecane as carrier. The mechanism of transport was investigated by studying various parameters like feed HNO3/NaNO3 concentration, OBDA concentration in the membrane, membrane pore size, membrane thickness etc. From these studies, the mechanism of transport was found to be diffusion controlled with diffusion co-efficient value of 5.1 × 10−6cm2/s. The membrane was found to be highly selective for tri- and tetravalent actinides, and trivalent lanthanides. OBDA based membrane was found to be stable for at least for ten consecutive cycles of operation. |
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