Facilitated transport of trivalent actinides (Am, Cm), lanthanides (La, Eu, and Lu) and fission product (Sr) was
investigated from 1 M HNO3 into 0.5 M α-hydroxy isobutyric acid (α-HIBA) through polymer inclusion
membrane (PIM) consisting of cellulose triacetate (CTA) as a polymermatrix, 2-nitrophenyl n-octyl ether (NPOE)
as a plasticizer andN,N,N′,N′-tetraoctyl-3-oxapentanediamide (TODGA) as a
carrier. The transport of Cm(III) was higher as compared to Am(III) which was ascribed to the higher ionic potential of the former. Effect of ionic
potential was also demonstrated for lanthanides where the transport of Lu(III) wasmore as compared to
La(III). The experimental results indicated that the transport ofmetal ions was controlled by the diffusion of the metal–ligand complex in the membrane phase. |