Coordination polymers of palladium stabilized by dimethylaminoalkylselenolate and carboxylate ligands are reported. The reaction of [PdCl(SeCH₂CH₂NMe₂)]₃ with AgOTf followed by treatment with sodium acetate afforded [Pd⁰Pd^II₄(SeCH₂CH₂NMe₂)₃(OAc)₃](OTf)₂ (1) in which one of the Pd atoms is in the zero oxidation state. In the absence of NaOAc, a tetranuclear complex, [Pd^II₄(SeCH₂CH₂NMe₂)₄(OTf)](OTf)₃ (2), is isolated from the same reaction. Subsequent treatment with NaO₂CR afforded [Pd₄(SeCH₂CH₂NMe₂)₄(O₂CR)₄] (R=tBu (3) and Ph (4)). The re action of [PdCl(SeCH₂CH₂CH₂NMe₂)]₂ with AgOTf and NaOAc yielded an ionic binuclear complex, [Pd^II₂(SeCH₂CH₂CH₂NMe₂)₂(OAc)](OTf) (5). These complexes have been characterized by NMR spectroscopy, crystal structures, and in some cases by X-ray photoelectron spectroscopy, cyclic voltammetry and mass spectrometry. Complexes 1 and 5 are associated through secondary interactions and coordinate bonds, respectively, to generate polymeric structures in the solid state.