BARC/PUB/2011/0366

 
 

White light emission from sonochemically synthesized rare earth doped ceria nanophosphors

 
     
 
Author(s)

Dutta, D. P.; Manoj, N.; Tyagi, A. K.

Source

Journal of Luminescence, 2011. Vol. 131 (8): pp. 1807-1812

ABSTRACT

Undoped CeO2, and single and triple doped CeO2:M (whereM=Dy3+, Tb3+and Eu3+) nanophosphors  were synthesized through a simple sono chemical process and characterized by using X-raydiffraction  (XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), high resolution transmission electron microscopy (HRTEM), EDS and photoluminescence (PL) spectrophotometry. The TEM micrographs show that resultant nanoparticles have flower-likeshape. The doped samples showed multicolor emission on single wave length excitation. Energy transfer was observed from host to the dopantions. Characteristic blue emission from Dy3+ ions, green from Tb3+ ions and red from Eu3+ ions were observed. The CIE coordinates of the triple doped Ce0.86Dy0.005Tb0.055Eu0.08O2 nano flowers lie in the white light region of the chromaticity diagram and show promise as good phosphor materials for new lighting devices.

 
 
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