BARC/PUB/2004/0291

 
 

Novel polymer inclusion membrane containing a macrocyclic ionophore for selective removal of strontium from nuclear waste solution

 
     
 
Author(s)

Mohapatra, P. K.; Pathak, P. N.; Kelkar, A.; Manchanda, V. K.
(RCD)

Source

New Journal of Chemistry, 2004. Vol. 28 (8): pp. 1004-1009

ABSTRACT

A new polymer inclusion membrane (PIM) containing cellulose triacetate (CTA) as the monomer, di-tert-butylcyclohexano-  18-crown-6 (DtBuCH18C6) as the carrier and 2-nitrophenyl octyl ether (NPOE) as the plasticizer was developed for the selective transport of Sr2+from aqueous nitrate medium. Studies with crown ether concentration variation have indicated a linear dependence on the permeability coefficient (P) suggesting adiffusion mechanism for ion transport. Effects of membrane thickness, nature of plasticizer and plasticizer concentration on the transport of Sr2+were studied. The effect of feed acidity was also investigated for a possible application in the nuclear waste solution. Selective Sr2+ transport was observed in a synthetic waste solution containing metal ions such as UO22+, MoO22+, Zr4+, Ce3+, Nd3+, Ru3+, Pd2+, Ba2+and Cs+, etc., in 1 M HNO3and 2 M NaNO3. Greater than 70% transport of Sr2+ was observed in 24 h while most of the other metal ions were negligibly transported (<0.01%).

 
 
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