BARC/PUB/2011/1170

 
 

Ferromagnetism in Mn Doped ZnO Nanoparticles: An EPR Study

 
     
 
Author(s)

Jayakumar, O. D.; Kadam, R. M.; Tyagi, A. K.

Source

Nanoscience and Nanotechnology Letters, 2011. Vol. 3 (4): pp. 584-590

ABSTRACT

We report the synthesis of nominal 2 and 5 at.% Mn-doped ZnO nanocrystalline particles by a co-precipitation method followed by calcination at different temperatures. Transmission electron microscopy study and the Rietveld refinement of X-ray diffraction data revealed that these samples crystallize in the monophasic wurtzite structure. DC magnetization measurements of these samples, calcined at 675 K, showed that while nominal 2 at.% Mn-doped ZnO is ferromagnetic above room temperature, 5 at.% Mn-doped ZnO exhibited a paramagnetic behavior. A distinct ferromagnetic resonance (FMR) signal observed in the EPR spectra of 2 at.% Mn-doped ZnO further confirmed its room temperature ferromagnetism. EPR measurements were used to estimate the number of spins participating in ferromagnetic ordering of these compounds.

 
 
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