Author(s) |
Jayakumar, O. D.; Sudakar, C.; Persson, C.; Salunke, H. G.; Naik, R.; Tyagi, A. K. |
Nanoparticles of Zn0.95-x Co0.05InxO (x=0.0 to 0.07) were synthesized by the pyrolitic reaction of sol-gels obtained from respective metal precursors. X-ray diffraction and high-resolution transmission electron microscopy studies confirm the formation of impurity-free wurtzite type ZnO structure for all the compositions. While pristine ZnO is diamagnetic,
Zn0.95Co0.05O nanoparticles show weak paramagnetic behavior at room temperature. When "In." is codoped with Co with x=0.0 to 0.07 in
Zn0.95-xCo0.05InxO, a systematic increase in magnetic moment is observed up to x=0.07. First-principles modeling supports that the ferromagnetic phase become more favorable at higher indium doping concentrations. |