BARC/PUB/10//1015

 
 

Enhancement of ferromagnetic properties in Zn0.95 Co0.05O nanoparticles by indium codoping: An experimental and theoretical study

 
     
 
Author(s)

Jayakumar, O. D.; Sudakar, C.; Persson, C.; Salunke, H. G.; Naik, R.; Tyagi, A. K.

ABSTRACT

Nanoparticles of Zn0.95-x Co0.05InxO (x=0.0 to 0.07) were synthesized by the pyrolitic reaction of sol-gels obtained from respective metal precursors. X-ray diffraction and high-resolution transmission electron microscopy studies confirm the formation of impurity-free wurtzite type ZnO structure for all the compositions. While pristine ZnO is diamagnetic, Zn0.95Co0.05O nanoparticles show weak paramagnetic behavior at room temperature. When "In." is codoped with Co with x=0.0 to 0.07 in Zn0.95-xCo0.05InxO, a systematic increase in magnetic moment is observed up to x=0.07. First-principles modeling supports that the ferromagnetic phase become more favorable at higher indium doping concentrations. 

 
 
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