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Author(s) |
Malghe, Y. S.; Dharwadkar, S. R.; Krishnan, K.; Singh Mudher, K. D.
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The phase transitions in the LaCrO3 were studied using bulk dilatometry and high temperature X-ray diffractometry from room temperature
to 1050 and 1200°C, respectively. LaCrO3 was prepared at 500°C from oxalate precursor employing microwave heating
technique. Bulk shrinkage measurements on LaCrO3 pellets
were carried out using dilatometer designed and fabricated in our own
laboratory. Dilatometric curves of LaCrO3 showed two peaks in
DL/L
vs. temperature curves in the range 200–400 and 800–1000°C,
respectively. These phase transitions have been confirmed using high temperature X-ray diffractometry. The role of simple
technique like bulk dilatometry in detecting and monitoring the polymorphic
transformations in solids is discussed for lanthanum chromates.
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