BARC/PUB/09/0362

 
  Dilatometry and high temperature x-ray diffractometry study of LaCrO3 prepared using microwave heating  
     
 
Author(s)

Malghe, Y. S.; Dharwadkar, S. R.; Krishnan, K.; Singh Mudher, K. D.

ABSTRACT

The phase transitions in the LaCrO3 were studied using bulk dilatometry and high temperature X-ray diffractometry from room temperature to 1050 and 1200°C, respectively. LaCrO3 was prepared at 500°C from oxalate precursor employing microwave heating technique. Bulk shrinkage measurements on LaCrO3 pellets were carried out using dilatometer designed and fabricated in our own laboratory. Dilatometric curves of LaCrO3 showed two peaks in DL/L vs. temperature curves in the range 200–400 and 800–1000°C, respectively. These phase transitions have been confirmed using high temperature X-ray diffractometry. The role of simple technique like bulk dilatometry in detecting and monitoring the polymorphic transformations in solids is discussed for lanthanum chromates.

 
 
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