BARC/PUB/2003/0478

 
 

Fragmentation of cesium-carbon cluster anions CsCn- (n≤10)

 
     
 
Author(s)

Gupta, A. K.; Krishnamurthy, M.
(NPD)

Source

Physical Review-A, 2003. Vol. 67 (2): Article no. 23201

ABSTRACT

We present the fragmentation dynamics of CsCn (n≤10) in collision with argon at 15 keV impact energy. The propensity for the formation of the fragment ions Cm (mn) exhibits even-odd oscillations, with the yield being larger when m is even; and this is correlated with the larger electron affinity of the product ion when m is even. We observe C3 loss in the case of CsC9 clusters. We find an unexpected oscillatory pattern in the kinetic-energy release (KER) spectra of Cn fragments. The ratio of the width of Cn to the parent CsCn, which is a measure of the KER in the center-of-mass (c.m.) frame, shows even-odd oscillation, with the ratio being larger when n is even than when n is odd. The oscillatory pattern is correlated with differences in fragmentation pathways accessed in the Franck-Condon region. Applying the reflection method with model potentials for two different   fragmentation paths, we find that the KER in the c.m. frame oscillates if an ion-pair formation pathway is preferred for clusters of even n.

 
 
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