The facile synthesis and characterisation of several new dimeric ( η3-allyl)palladium (II) complexes of the type, [Pd(μ-L)2 (η3-C3H4R)2] [R = H or Me; LH = 4-CH3C6H4SH; 3,5-R’2pzH (R’ = But or Ph]; ArNNNHAr (Ar = 4-FC6H4); PhNC(Ph)NHPh] are reported.