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Author(s) |
Nailwal, B. C.; Goswami, N.; Lenka, R. K.; Singha, A. K.; Fani, H. Z.; Rao, A. S.; Ghosh, A.; Bindal, R. C.; Mohan, S.; Kar, S. (MDS;PMD;CTD;G&AMD;HWD)
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Source |
International Journal of Hydrogen Energy, 2020. Vol. 45 (46): pp. 24341-24354 |
ABSTRACT
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HIx processing section of Iodine-Sulphur (IS) thermochemical cycle dictates the overall efficiency of the cycle, which poses extremely corrosive HI–H2O–I2 environment, coupled with a very low equilibrium conversion (~22%) of HI to hydrogen at 450 °C. Here, we report the fabrication, characterization and operation of a 4-tube packed bed catalytic tantalum (Ta) membrane reactor (MR) for enhanced HI decomposition. Gamma coated clay-alumina tubes were used as supports for fabrication of Ta membranes. Clay-alumina base support was fabricated with 92% alumina (~8 μmparticle size) and 8% clay (~10 μmparticle size), sintered at a temperature of 1400 °C. An intermediate gamma alumina coating was provided with 4% polyvinyl butyral as binder for a 10% solid loading. Composite alumina tubes were coated with thin films of Ta metal of thickness <1 μm using DC magnetron sputter deposition technique. The 4-tube Ta MR assembly was designed and fabricated with integration of Ptalumina catalyst for carrying out the HI decomposition studies, which offered >80% singlepass conversion of HI to hydrogen at 450 °C. The hydrogen throughput of the reactor was ~30 LPH at a 2 bar trans- embrane pressure, with >99.95% purity. This is the first time a mutitube MR is reported for HIx processing section of IS process. |
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