BARC/PUB/2021/0735

 
 

Cr3+ assisted energy transfer for Mn2+ doped zinc gallogermanate with narrow and bright green emission

 
     
 
Author(s)

Srivastava, B. B.; Gupta, S. K.; Mohan, S.; and others
(RCD)

Source

Materials Letters, 2021. Vol. 297: Article no. 129964

ABSTRACT

The objective of this work is to obtain bright green and tunable emission by dopant engineering. It has been achieved in zinc gallogermanate (ZGG) nanodiscs by utilizing Mn2+and Cr3+ions as dopant and codopant, respectively. Based on photoluminescence measurement, we have found that the Cr3+ codopant triggers bright green emission of Mn2+ dopant in the nanodiscs by acting as a bridge to efficiently transfer the emission from the ZGG host to Mn2+ion. We have validated the efficacy of energy transfer by concentration dependent photoluminescence and lifetime measurement. There are only a few reports on green emitting bulk Mn2+ doped ZGG. This work highlights the strategy of chromium co-doping in enhancing its green emission as a nanostructure, which could be extended to other hosts.

 
 
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