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Author(s) |
Malavi, P. S.; Karmakar, S.; Patel, N. N.; Bhatt, H.; Sharma, S. M. (HP&SRPD)
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Source |
Journal of Physics-Condensed Matter, 2014. Vol. 26 (12): Article no. 125701 |
ABSTRACT
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Optimally doped ironchalcogenide superconductor Fe1.03Se0.5Te0.5 has been investigated under high pressures using synchrotronbased x-ay diffraction and midinfrared reflectance measurements at room temperature. The superconducting transition temperature .(Tc)of the same sample has been determined by temperaturedependent resistance measurements up to 10 GPa. The tetragonal phase (P4/nmm) is found to exist in phaseseparated states where both the phases have remarkably high compressibility. A firstorder structural transition to the orthorhombic phase (Pbnm) is reported above ~10 GPa. For the tetragonal phase, a strong correlation is observed between the Fe(Se,Te)4 tetrahedral deformation and the sharp rise of Tcup to ~4 GPa, above which Tcshows marginal pressure dependence at least up to ~10 GPa. The evolution with pressure of the optical conductivity shows that with increasing pressure the tetragonal phase approaches towards a conventional metallic state. Above ~6 GPa, the Drude term reduces drastically, indicating poor metallic character of the highpressure orthorhombic phase. |
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