Forty brands of tobacco used in Indian cigarettes, 20 brands of bidis (tobacco rolled in wrapper leaves), 15 brands of chewing tobacco and 15 brands of snuff tobacco were analyzed by nuclear and allied techniques. The elements measured into tobacco can be grouped in to seven categories from less than 1 ppm to 5% by weight. Concentration level varied from 0.5–5% for (Ca, K, Cl), 400–1500 ppm (Fe), 200–600 ppm (Na),100–300 ppm (Ti, Mn, Br and Sr), 10–100 ppm (Cu, Zn and Rb), 1–10 ppm (Cr, Ni, Pb and La) and less than 1 ppm (As, Co, Cd, Sb, Hg and Eu).Among the above elements Cr, Ni, As, Cd, Pb, Hg and Sb are considered toxic. The percentage transfer of the elements from cigarette tobacco to smoke particles during smoking was also estimated using a smoking machine and collecting the smoke particles on a filter paper.The results show that Br, Cr, Sb and Zn have high percentage transfer from tobacco to its smoke of the order of 2–15%. Out of these Sb has the highest 15%.Cobalt, Fe and Sc have lowest percentage of transfer of the order of less than 1%. The percent transfer of these elements from tobacco to tobacco smoke is higher in case of bid is (1.5–3.0 times) as compared to cigarettes. In cigarettes also non-filter cigarettes have highe r transfer (2–3 times) as compared to filter tip cigarettes.