An attempt has been made to synthesize ceramic titania and zirconia membranes by sol-gel process by filtering respective viscous colloidal sol through microporous alumina support and gelling followed by sintering at 400^◦C and 470^◦C respectively. The static charge on the pores of the so formed membranes and the pore size istribution determine the applicability in filtering colloidal solution. The mean pore size from SEM were found to be .65 μm and 0.54 μm for titania and zirconia membranes respectively with 1.47×10⁷/cm² as pore density for both. The filtration characteristics during membrane layer formation showed that the membrane layer formation started after 35 minutes in the case of titania membrane and 40 minutes in the case of zirconia membrane. From the gravimetric estimation of water content of the membranes the thickness of the membrane was found out to be 3 μm and the porosity was found out to be 0.30 for both the cases. The particle charge density was estimated from the zeta potential and the particle size. The pore charge density was estimated from the particle charge density, pore density, pore diameter and the thickness of the membrane layer. The membrane pore charge density was found to vary between 3 to−1μ Coulombs/cm² in the case of titania membrane and 7 to −0.5 μ Coulombs/cm² in the case of zirconia membrane in the pH range 1–12.