In this paper we propose a way to use optical polarisation observations to provide independent constraints and guide to the modelling of the spectral energy distribution (SED) of blazars, which is particularly useful when two-zone models are required to fit the observed SED. As an example, we apply the method to the 2008 multiwavelength campaign of PKS 2155-304, for which the required polarisation information was already available. We find this approach succesful in being able to simultaneously describe the SED and variability of the source, otherwise difficult to interpret. More generally, by using polarisation data to disentangle different active regions within the source, the method reveals otherwise unseen correlations in the multiwavelength behaviour which are key for the SED modelling.