BARC/PUB/2016/1189

 
 

Ni 3d – O 2p hybridization dependent magnetic properties of LaNiO3 thin films

 
     
 
Author(s)

Yogesh Kumar; Singh, A. P.; Sharma, S. K.; and others
(SSPD)

Source

Thin Solid Films, 2016. Vol. 619: pp. 144-147

ABSTRACT

We present here the study on magnetic properties and their relation to the electronic structure for c-axis oriented LaNiO3 films deposited on LaAlO3 single crystals using the rf-magnetron sputtering. Swift heavy ion irradiation induced annealing alters the unusual temperature dependent magnetic behaviour of pristine film to the paramagnetic one. X-ray absorption spectroscopic measurements, performed at O K-edge and Ni L-edge, reveal that NiO hybridization is increased after the initial irradiation. Charge-transfer multiplet calculations of the Ni L-edge indicate that variation of magnetic behaviour can be related to the NiO hybridization strength inducing a further variation in Ni spin state.

 
 
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