BARC/PUB/2005/0410

 
 

Studies on high pressure behavior of carbon nanotubes: X-ray diffraction measurements using synchrotron radiation

 
     
 
Author(s)

Karmakar, S.; Sharma, S. M.; Sood, A. K.
(BARC)

Source

Nuclear Instruments and Methods in Physics Research B, 2005. Vol. 238: pp. 281-284

ABSTRACT

High-pressure behavior of novel one-dimensional material – carbon nanotubes (single-walled and multi-walled, pris-tine and Fe-filled) have been investigated by in situ powder X-ray diffraction (XRD) studies. Single-walled nanotubes show remarkable mechanical resilience. The presence of non-hydrostatic stresses makes compression behavior much different from that under the hydrostatic stress. Our results also suggest pressure-induced elliptization of the tubes in a bundle. Iron-filled multi-walled nanotubes, unlike pristine, show a structural modification at a pressure of ~9 GPa where the outer component (Fe3C) of the encapsulated nanowire undergoes an iso-structural transition. Also the high-pressure behavior of the a-Fe is quite different from the bulk

 
 
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