BARC/PUB/2013/0728

 
 

Electrochemical study on corrosion behaviour of zircaloy-2 in aqueous medium containing permanganate ion

 
     
 
Author(s)

Sumathi, S.; Bera, S.; Rangarajan, S.
(W&SCD)

Source

Corrosion Engineering Science & Technology, 2013. Vol. 48 (4): pp. 294-302

ABSTRACT

The corrosion compatibility of zircaloy-2 was studied in strong oxidising permanganate based acidic (HMnO4) medium using impedance spectroscopy and potentiodynamic anodic polarization methods at room temperature (28°C) and elevated temperatures (65 and 90°C). The average corrosion rate of zircaloy-2 in HMnO4 medium (0.417–8.33 mM) was found to be 1.32 X 10-4 μm h-1 at 28°C, 2.59 X10-4 μm h-1 at 65°C and 3.53 X10-4 μm h-1 at 90°C. At 28°C, the polarisation resistance Rp values obtained from impedance spectrum were higher (in kΩ) when compared to Rp values at 65 and 90°C, indicating a lower corrosion rate at lower temperature. Comparative studies with 2.5 mM H2SO4 and platinum (as a working electrode) showed the effects of oxidising nature and participation of additional redox reactions in HMnO4 medium. Cyclic polarisation studies showed the absence of pitting attack on zircaloy-2.

 
 
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