Photostimulated luminescence (PSL) of CsBr_{1 – x}Cl_x:Eu^{2 +} system has been studied for different europium concentrations. Two types of F centers have been formed due to bromide ion vacancy and chloride ion vacancy. The formation of Eu^{3 +} has been confirmed by optical absorption studies. PSL of CsBr_{1 – x}Cl_x:Eu^{3 +} is found to exhibit bands at 415, 420, 440 and 470 nm. The results are presented and discussed in this paper.