BARC/PUB/2013/0510

 
 

Air-stability and bending properties of flexible organic field-effect transistors based on poly[N-9′-heptadecanyl-2, 7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′, 3′-benzothiadiazole)]

 
     
 
Author(s)

Jha, P.; Koiry, S. P.; Saxena, V.; Veerender, P.; Gusain, A.; Chauhan, A. K.; Debnath, A. K.; Aswal, D. K.; Gupta, S. K.
(TPD)

Source

Organic Electronics, 2013. Vol. 14 (10): pp. 2635-2644

ABSTRACT

We have fabricated flexible field-effect transistors (FETs) using poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)], PCDTBT, as an active channel, poly(methyl methacrylate) (PMMA) as gate dielectric and biaxially oriented polyethyleneterephthalate (BOPET) as supporting substrate. The output and transfer characteristics of the devices were measured as a function of channel length. It has been observed that various OFET parameters viz. on–off ratio (~105), mobility (μ ~ 10-4 cm2 V-1 s-1), threshold voltage (Vth ~-14 V), switch-on voltage (Vso ~-6 V), subthreshold slope (S ~ 7 V/decade) and trap density (Nit  1014 cm-2 V-1) are almost independent of the channel length, which suggested a very high uniformity of the PCDTBT active layer. These devices were highly stable under atmospheric conditions (temperature: 20–35oC and relative humidity: 70–85%), as no change in mobility was observed on a continuous exposure for 70 days. The studies on the effect of strain on mobility revealed that devices are stable up to a compressive or tensile strain of 1.2%. These results indicate that PCDTBT is a very promising active layer for the air stable and flexible FETs.

 
 
SIRD Digital E-Sangrahay