BARC/PUB/2003/0093

 
 

Reactive magnetron sputter deposition of chromium nitride coatings

 
     
 
Author(s)

Singh, K.; Grover, A. K.; Suri, A. K.
(MPD)

Source

Transactions of the Institute of Metal Finishing, 2003. Vol. 81 (4): pp. 131-135

ABSTRACT

Chromium nitride coatings were deposited by reactive D.C. magnetron sputtering on stainless steel substrates varying the substrate biasing voltage and nitrogen flow rates and using chromium plated (>200 μm thick) stainless steel as the target (cathode). Coatings were characterised by X-ray diffraction analysis for the phases present and surface hardness values were measured by Knoop indentor. Electrochemical evaluation of the coatings was performed in de aerated I M H2SO4 solution at room temperature. CrN coatings had the typical hardness values ranging from 1300 -1600 HK25. Increase in nitrogen flow (to total gas) from 9.5 to 13 % caused the corrosion resistance to increase rapidly (JCTT reduced from 15/.4 to 54 μA cm-2). Further increase in nitrogen flow ratio to 23% increased the corrosion resistance but very gradually. Increase in nitrogen flow beyond 23% caused the corrosion resistance to decrease. Coatings with the minimum current in the passive region were found to be those deposited at a FN2 /F1 of 16. 7%, the coating with the maximum hardness (1790 HK25) showed the presence of CrTN as tile major phase. Increase in substrate biasing (-50 to -250 V) resulted in an increase in orrosion resistance (JTT reduced from 159.6 to 18.4 μA cm-2).

 
 
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