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Author(s) |
Errandonea, D.; Lacomba-Perales, R.; Ruiz-Fuertes, J.; Segura, A.; Achary, S. N.; Tyagi, A. K.
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Room temperature angle-dispersive x-ray
diffraction measurements on zircon-type EuVO4, LuVO4,
and ScVO4 were performed up to 27 GPa. In all the
three compounds we found evidence of a pressure-induced
structural phase transformation from zircon to a scheelite-type
structure. The onset of the transition is near 8 GPa, but the
transition is sluggish and low-pressure and high-pressure phases
coexist in a pressure range of about 10 GPa. In EuVO4
and LuVO4 a second transition to a M-fergusonite-type
phase was found near 21 GPa. The equations of state for the
zircon and scheelite phases are also determined. Among the three
studied compounds, we found that ScVO4 is less
compressible than EuVO4 and LuVO4, being
the most incompressible orthovanadate studied to date. The
sequence of structural transitions and compressibilities are
discussed in comparison with other zircon-type oxides.
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